Enolization Reactions Mediated by S-Block Metal Amide Reagents

Editora:

KS OmniScriptum Publishing

Código:

491_9783838300160

Vendido e entregue por Um Livro

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The enolization of ketonic substrates is acornerstone reaction in modern organicsynthesis. The research in this book is split intothree main sections, with the investigation ofs-block metal enolate chemistry being the underlyingtheme: The first section focuses on the synthesis andcharacterization of a series of homo- andheterobimetallic potassium and calcium enolates. Thesecond section concentrates on an investigation intothe utility of Ca(HMDS)2 to mediate the enolizationof ketonic substrates. The final section outlines adetailed mechanistic study for the enolization ofpropiophenone mediated by Mg(HMDS)2 in toluene.

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