1. General Introduction.- 2. Application of Group 5 Polyoxometalate as an Efficient Base Catalyst: a Case Study of [Nb10O28]6-.- 3. Effect of Counter Cation on the Base Catalytic Activity of [Nb10O28]6-.- 4. Lewis Base Catalytic Properties of [Nb10O28]6- for CO2 Fixation to Epoxide: Kinetic and Theoretical Studies.- 5. Superior Base Catalysis of Group 5 Hexametalates over Group 6 Hexametalates.- 6. Concluding Remarks.
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